Stock-footage from Republic Pictures' earlier Zorro serials was served up once again in this 12 chapter cliffhanger, this time without the financially strapped studio having to credit Zorro creator Johnston McCulley or pay any royalties. Zorro simply became "Don Daredevil" (Ken Curtis), a foppish Easterner by day turned masked avenger by night. Like his not too distant relative, Don wore his disguise in order to battle nasty Roy Barcroft who, under a forged Spanish land grant, attempts to take over the surrounding ranch land.

A group of ranchers, led by Colonel Arnold and Ward Gordon, are drilling an oil well but getting fierce opposition from an unknown gang of outlaws. Eastern promoter J.B."Dude" Dawson, is behind the gang as he is out to prevent the co-op members from striking oil before their lease expires, so he can secure the property for his company. When Ward, with the help of Arnold and his daughter Sally, arranges for a new driller to be brought in, the replacement man is killed and one of Dawson's men takes his place.

Finding Indians stealing from his ranch, Gene learns they are suffering from malnutrition. Store owner Martin is cheating them and now he is after the Chief's valuable necklace. When the dying chief is found, having been attacked and robbed, Martin blames Lakhona who would become the new chief. When Gene helps Lakhona they soon find themselves fleeing from the law.

Jean Loring has her men illegally killing and selling game. Roy suspects her and gets himself invited to stay at her ranch. Investigating he finds the freezer where the slaughtered game are kept. But he is caught, tied up, and left to freeze.

Lt. Col. Glenn Manning is inadvertently exposed to a plutonium bomb blast and although he sustains burns over 90% of his body, he survives. Then he begins to grow, but as he grows he starts losing his mind. By the time he stops he is 50 ft tall, insane and is on the rampage.

Gridley is mining silver from an old Mexican mine and bringing it into the USA thru a passage into his worthless mine. Border guard Rogers suspects Gridley and finally finds the secret entrance to the Mexican mine. He sends Lee Madison for help only to have her captured by Gridley. Trigger brings help that takes care of Gridley's men and now Roy has to rescue Madison.

Rod Serling's seminal anthology series focused on ordinary folks who suddenly found themselves in extraordinary, usually supernatural, situations. The stories would typically end with an ironic twist that would see the guilty punished.